Accurate pronunciation at the outset should never be overstated. There are many books you can refer to, but here I just want to make it simple and I would like you to follow those steps when practise pronunciation:
Listen->Mimic->Practice->Correct
Just repeat the above steps until you find yourself speak exactly the same as the sample sound.
CC's Note:
Do NOT even think about the corresponding characters and their meaning when you pronounce some words. Just focus on the pronunciation first!
A syllable is composed of three parts:
(1) Initial;
(2) Final;
(3) Tone (4 of them).
For example:
wō contains 3 parts:
w (initial) + o (final) + -(tone)
Our experience is that people usually confuse (1) and (2) with their home tongue (e.g., the pronunciation of 'j'), and cannot remember what the 4 tones sound like. It can be overcome just by some effort.
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